Beilstein J. Org. Chem.2011,7, 1–8, doi:10.3762/bjoc.7.1
to alkenes bearing a wide range of functional groups [8][9][10][11]. Especially, the olefin cross-metathesis with oleochemicals offers a versatile synthetic approach to prepare value-added substrates starting from renewablerawmaterials. Due to the cross-metathesis reactions of fatty acid
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Graphical Abstract
Scheme 1:
Cross-metathesis of methyl oleate (1) with cis-2-butene-1,4-diyl diacetate (2) and the self-metathe...
Beilstein J. Org. Chem.2010,6, 1149–1158, doi:10.3762/bjoc.6.131
; metathesis; olefin isomerization; renewablerawmaterials; ruthenium–indenylidene catalysts; Introduction
Among the large number of organic and organometallic reactions allowing the formation of carbon–carbon bonds, olefin metathesis has found its place in organic synthesis as well as polymer science as a
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Graphical Abstract
Figure 1:
Olefin isomerization during ADMET polymerization.